Sulfide
In
chemistry, a
sulfide (
sulphide in
British English) is a combination of
sulfur with an
oxidation number of -2, with another
chemical element or a
radical thereof. A few
covalent sulfur compounds, such as
carbon disulfide (CS
2) and
hydrogen sulfide (H
2S) are also considered to be sulfides.
Hydrogen sulfide gas has the odor of rotten eggs, and is also highly toxic. It is formed biologically in the sediments of swamps and in the treatment of sewage sludge by anaerobic digestion of sulfur containing proteins, or bacterial reduction of sulfates. It also occurs in the emissions of some volcanoes, and as a byproduct of some industrial processes.
Uses
- Cadmium disulfide (CdS2) can be used in photocells.
- Calcium polysulfide ("lime sulfur") is a traditional fungicide in gardening.
- Carbon disulfide (CS2) is sometimes used as a solvent in industrial chemistry.
- Sodium sulfide (Na2S) is an important industrial chemical, used in manufacture of kraft paper, dyes, leather tanning, crude petroleum processing, treatment of heavy metal pollution, and others.
- Zinc sulfide (ZnS) is used for lenses and other optical devices in the infrared part of the spectrum.
- Zinc sulfide with a trace of copper is used for photoluminescent strips for emergency lighting and luminous watch dials.
- Several metal sulfides are used as pigments in art, although their use has declined somewhat due to their toxicity. Sulfide pigments include cadmium, mercury, and arsenic.
Natural occurrence
Many important metal ores are sulfides. Significant sulfide minerals include:
Safety
Many sulfides are significantly toxic by inhalation or injection, especially if the metal ion is toxic. Additionally many sulfides, when exposed to a strong mineral acid, will release toxic hydrogen sulfide - and this includes your stomach acids!
Also, many sulfides are somewhat flammable, and a few are highly flammable. When a sulfide burns, the fumes usually include toxic sulfur dioxide (SO2) gas.
See also sulfate, sulfite.