Sienna, in and of itself, is sometimes referred to as "raw sienna", in order to differentiate it from "burnt sienna", which is a more common pigment than the raw form. The difference is in the process applied to burnt sienna, which is raw sienna heated to remove the water from the clay and redden its brownish colour.
The name derives from the most notable Renaissance location for the earth, Siena, Italy, and is short for terra di Sienna, "earth of Sienna". The mines used to produce this sienna petered out in the 1940s. Much of today's sienna production is still in Italy's offshore islands, Sardinia and Sicily, while other major deposits are found in the Appalachian Mountains, where it often goes hand-in-hand with the region's iron deposits.
Many of these deposits date back to the Precambrian, and are pointed to as evidence of the Snowball Earth hypothesis.