All the atoms of a particular radioactive species have the same probability of disintegrating in a given time, so that an appreciable sample of radioactive material, containing many millions of atoms, always changes or disintegrates at the same rate. This rate at which the material changes is expressed in terms of the half-life, the time required for one half the atoms initially present to disintegrate, which is constant for any particular isotope.
The half-life is shorter than the average lifetime. The half-life is ln 2 ≈ 0.693 times the average life. If this seems strange, note that the life of half of the particles is only somewhere between 0 and the half-life, while the life of the other half can be anywhere between the half-life and infinite.
Half-lives of radioactive materials range from fractions of a second for the most unstable to billions of years for those which are only slightly unstable. Decay is said to occur in the parent nucleus and produce a daughter nucleus. Decay from a parent to a daughter nucleus may produce alpha, beta particles, and neutrinos. Gamma radiation may be produced as the nucleus is de-excited but this is only after the alpha or beta decay has taken place. Radioactive decay results in a mass loss, which is converted to energy (the disintegration energy) according to the formula E = mc2. Often, the daughter nucleus is also radioactive, and so on down the line for several successive generations of nuclei until a stable one is finally reached. The three such naturally occurring series are shown in the following table:
|Series||Starting Isotope||Half-Life (years)||Stable End Product|
Note: there are naturally occurring radioactive isotopes (such as C-14) but they are not part of a series.
Other applications of the half-life concept
The concept of half life is not restricted to the decay of radioactive nuclei. The law is also useful in many processes where the rate of change of some property of a system depends itself on this property. In some chemical reactions, the rate of reaction depends on the concentration of a particular reactant. During the course of the reaction this concentration decreases, causing the rate of reaction also to go down. It is found that the time taken for the rate of reaction to halve is constant, if the reactant is said to be first order with respect to the rate. Enzyme-catalyzed reactions fall into this category.
Half life is also important in calculating populations, although it is only applicable where the resources available to the population remain surplus to the needs. In these situations the population and its demands increase rapidly, so in reality the resources are always a limiting factor.